Water Poison team:
Water MC Sasuke Naruto
x Iruka x
Talent : 3 2 3 2 2 or 2 2 3 2 2 ( suggest 3 2 3 2 2 ).
Summon Gamachu or Gamaken.
Poison Tail work on Naruto's mystery.
U can swap into water clone if you want but i don't think it's a good idea.
Note : Put Iruka when you place 3 ninjas in their position so he can buff for Naruto's clone.

Fire :
Fire MC Tobi x
Iruka Hinata x
x x x
Talent 3 3 3 2 1 or 2 3 3 2 1 ( suggest 3 3 3 2 1 for cc )
Yup ! This team is really strong in controlling and high DOTs, but u must do my note with water main above to make shields for clone of main character.

Hope it will help you !