I have 2 favorite line ups.

Jigokudo 4th Hokage
Water Main Pakura

Talents 3 2 4 3 2

Summon: Chameleon/King of Hell/Other 10 Combo Chase

2 attacks each round on 4th Hokage so he can scale quicker.
Jigokudo healing 2 units removing 2 debuffs 2x. Yes plz
Water Main supporting with Healing Tips and Poison Tai,
Pakura offering Immobile and Ignite to the team while giving Jigokudo and 4th Hokage 2 attacks.

Then there is

Darui Kakashi Anbu
Kurenai LM

Talents: 2 3 1 1 3
Summon: Lightning Tiger King

Kurenai to reflect a debuff (Shisui/MM counter) and for Chaos on Chase for guaranteed CC
Kakashi Anbu to make LM untargetable from Mysteries. Deals a lot of damage to Non Konoha Ninjas, C*so kill Roshi round 1.
Darui to provide Barrier to increase Kakashi Anbu, LM, Darui's Damage
LM to provide Leech, and RoW to keep my ninjas for the most part immune. Then finishing anything off in round 1 that Kakashi Anbu didn't kill through mystery.