I think the ninja you're looking for here would be Kushina [Red Hot Habanero], her mystery seals immunity for a round, while her chase causes immobilization, her mystery can be used round one if you put her up front so that she takes damage and lowers her cooldown (though if you need a ninja that has their mystery available at the beginning, you may be out of luck, I'd recommend getting Han for that and just going with standard control from there). She also has the added bonus of being a wind type and female which lets her synergize with Wind Main fairly well.